Crystal structure of [2,6-di­fluoro-3-(pyridin-2-yl-κN)pyridin-4-yl-κC 4](pentane-2,4-dionato-κ2 O,O′)platinum(II)

نویسندگان

  • Ki-Min Park
  • Jieun Lee
  • Youngjin Kang
چکیده

The asymmetric unit of the title compound, [Pt(C10H5F2N2)(C5H7O2)], comprises one Pt(II) atom, one 2,6-di-fluoro-2,3-bi-pyridine ligand and one acetyl-acetonate anion. The Pt(II) atom adopts a distorted square-planar coordination geometry, being C,N-chelated by the 2,6-di-fluoro-3-(pyridin-2-yl)pyridin-4-yl ligand and O,O'-chelated by the pentane-2,4-dionate ligand. The two pyridine rings of the bi-pyridine ligand are approximately coplanar, making a dihedral angle of 1.2 (2)°. A variety of intra- and inter-molecular C-H⋯O and C-H⋯F hydrogen bonds, as well as π-π inter-actions [centroid-centroid distances = 4.337 (3) and 3.774 (3) Å] contribute to the stabilization of the mol-ecular and crystal structures, and result in the formation of a three-dimensional supra-molecular framework.

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[2,6-Di­fluoro-3-(pyridin-2-yl-κN)pyridin-4-yl-κC 4](penta­ne-2,4-dionato-κ2 O,O′)iridium(III)

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عنوان ژورنال:

دوره 71  شماره 

صفحات  -

تاریخ انتشار 2015